Lets start from the top...
Could it form naturally? Probably not.
Nitric Oxide (NO) is an unstable compound in its native form and, if exposed to any amount of Oxygen (including Ozone) it will steal an Oxygen atom to turn into Nitrogen Dioxide (NO2). The body of organic life on Earth produces NO, but it has a half-life of only a few seconds in blood before it can steal Oxygen to turn into NO2.
Nitrogen Dioxide (NO2) really isn't that much more stable than Nitric Oxide. The bond strength between the Oxygen and Nitrogen isn't very strong, and there is a free electron on the Nitrogen, making the whole compound a free radical. It reacts strongly with water, creating nitric acid...it is also highly reactive with alkalies and alchohols.
Nitrous Oxide (N2O), when exposed to oxygen, turns into Nitric Oxide, which (as discussed) then turns into Nitrogen Dioxide. So, ultimately, your atmosphere all wants to turn into NO2, which is still a very reactive compound.
Ultimately...your problem is this: Oxygen is very, very reactive, and Nitrogen forms weak bonds with it. All three of these compounds are strong oxidizers...meaning that they will freely give up their Oxygen atoms to many, many different compounds.
Moving on...will it be stable?
Your entire atmosphere is made of oxidizers...any compound that likes to react with oxygen is going to snatch it up. Nitrogen, by itself (N2), is very much non-reactive...this is why our atmosphere is stable on Earth, because most of the atmosphere is made of a compound that is chemically boring. You do NOT want your atmosphere to be reactive...otherwise, it will react with anything and everything, and your atmosphere will either change composition dramatically...or will cease to be an atmosphere.
I would also like to add that anyone attempting to live on this planet, suspending disbelief such that it may exist, would essentially live in a giant powder keg. You are in an extremely oxygen rich environment. All of those 'no smoking anywhere near this' signs that you see on pure oxygen tanks? That applies to the whole planet. With such high oxygen concentrations that oxides make up the vast bulk of your planet's atmosphere: Iron Is flammable. It rusts so rapidly that it burns.
I suppose I can toss this out there, even though this planet is unlikely to exist (for long, anyway...even if you terraformed it that way on purpose). But, your average global temperature, assuming normal 1 bar pressures, needs to stay above 70.2 degrees F, because that's the boiling point for NO2.
TL;DR: Your desired planet's atmosphere is highly reactive. This is Bad.