Setup
Ilithyia is a fictional super earth orbiting Eta Cassiopeia A, otherwise known as Achrid. She is 1.73 times larger than Earth and orbits closer to her host star, with a solar irradiance of $2300 \frac{W}{m^2}$. When the story takes place the atmospheric surface pressure is ~0.3 bar and the exoplanet is virtually devoid of $H_2O$.
Problem definition
The fact that Ilithyia has almost no $H_2O$ is fine in isolation, but it becomes paradoxical with the low pressure. Lets take a step back and examine what Ilithyia´s early planetary evolution most likely resembled.
Shortly after her formations large oceans formed, similar to Earth and Venus. These oceans quickly evaporated due to the high solar irradiance, triggering a runaway greenhouse effect. On Earth and Venus this caused atmospheric pressures to surpass 100 bar. Ilithyia is a lot larger than either, so pressures would be lower. Around 30 - 40 bar. On Earth, tectonic activity, water, and life bonded atmospheric $CO_2$ into solids, most commonly calcium carbonate through lithification. This did not happen on Venus. There, $H_2O$ was broken apart by the sun and the hydrogen carried away into space. Something similar would have happened on Ilithyia.
This is where the paradoxic requirements come in play. Ilithyia having little water is reasonable. The atmosphere being this thin isn't. Ilithyia is very large, and without oceans, plate tectonics would have shut down. Simply speaking, there is no geological process left to remove $CO_2$ from the atmosphere. Ilithyia should look like Venus, but she does not. What happened? Where is the $CO_2$?
Life... uhm... finds a way
The primary difference between early Venus and Ilithyia is life. On Ilithyia life evolved as soon as the oceans formed. It used thermosynthesis to power its glucose-producing biochemistry and did not evolve multicellularity before the oceans evaporated.
Thermosynthesis might be the saving grace here because the one thing "Venus" Ilithyia isn't short of is a massive, readily available, thermal gradient. On Earth, deep sea life often exploits convection currents around hydrothermal vents for chemosynthesis. Something similar would happen here: life could ride convection currents to dip in and out of the lower atmosphere, pick up heat, and perform work in the stratosphere.
The biochemistry life uses cannot exist in the lower atmosphere. Glucose, for instance, would just decompose. So it would have to evolve a thermal insulation layer around the cell wall. A foamy / spongy material like aerogel or Starlite. This works on a surface level but does not directly solve the core problem. Life is the only way to remove $CO_2$ from the atmosphere. But to do so, it has to bind the gas into a solid by itself. On Earth most calcite is made by sediment, organic materials, undergoing lithification. This does not happen on Ilithyia. There cannot be a sediment in-between step. When life dies, what it leaves behind has to permanently trap carbon dioxide. The only way I can see this working is if the thermal insulator unicellular organisms evolve is itself made of $CO_2$ and doesn't break apart under the surface conditions. So, when these organisms die, their thermal insulator remains and over the eons they slowly bind most $CO_2$ in it.
Requirement Hell
Let's take a step back and examine what I need this thermal insulator to be, and you will see why it has been difficult to find one. It must:
- utilize Carbon
- be resistant to large temperatures, pressures, and acidic conditions for an extended period of time
- be capable of forming aerogel-like structures to perform well as a lightweight insulator
- be "manufacturable" by a unicellular organism
There are loads of organic insulators which could work, but those won't last long enough on the surface to trap $CO_2$. Similarly, those materials which do trap $CO_2$ like calcite don't make great aerogel material. Looking at real world "Starlite" derivatives those often use baking soda, otherwise known as sodium bicarbonate. The issue there is that these are more ablative materials. $NaHCO_3$ decomposes to $Na_2CO_3$ at only a few 100 degrees Kelvin, which then decomposes into $CO_2$. Great for carrying away heat, not so good if you want to trap the $CO_2$.
The Chemical Garden
There are two silver linings to this. First, thermosynthesis once again comes in clutch. Since we assume that the organisms exploit the atmosphere's thermal gradient it is also safe to say they have access to the whole range of chemicals within it. While Ilithyia has no tectonic activity, there are massive volcanic traps spewing out chemicals. For instance, the solution could include magnesium even if we wouldn't expect to find any of that in the stratosphere.
Second, the solution doesn't have to be one size fits all. I don't think the most evolutionary sound strategy is to build a rock around a cell. For all I care, the thermal insulator can be decomposed 90% by the atmosphere so long as some of it traps $CO_2$. To give an example, maybe the insulator uses calcite pebbles woven in an otherwise organic / regrowing lattice. The lattice would break apart once the organism is dead, but the calcite pebbles remain. That would be a "good enough" solution. But I have no idea if that is reasonable.
Hard Sci-Fi?
I tagged this as science-based
because there is no hard sci-fi. For all we know a seemingly perfect solution could be invalidated by some weird chemical reaction that only happens on an exoplanet of this mass due to unknown reasons XYZ. Moreover, the moment life is involved simplistic assumptions about the atmosphere do not apply anymore. We don't know what the exact transition from a liquid to gaseous habitat in Ilithyian life did to the atmosphere and that is just impossible to find out.
What I am looking for is a solution that fits the criteria described above. The most important thing it has to do is offer one path for $CO_2$ removal.
Thank you for reading, and any help!
EDIT: Details as requested:
For Ilithyia:
- Day length: 11.32 hours (no natural moon)
- Atmospheric height during "Venus" phase: ~200 km
- Temperature laps rate similar to Venus, so 700-ish Kelvin on the surface, drop to about 300-400 Kelvin 30-40 km up
Regarding life, this is more speculative. I would suspect the unicellular organisms have to be relatively large, perhaps starting at 10 micrometers. This is based on the insulation layer.