I like the idea of using the electricity to rob the target of whatever heat it has.
I'm just gonna think outloud on that bit alone.
Idea 1) It's almost like how we use lasers to cool down a handful of cesium atoms to do research on them. The thing is they're in a very very controlled container where the atoms are being shined on from 6 directions just below the absorption frequency, so a Doppler effect takes place if the atom is moving towards a laser, absorbs it, and slows down. I don't know what 100 years from now looks like but you would have to figure out what your target is made of and throw photons at it with just the right wavelength at specific atoms, haha. But it would only be coming from one direction, not 6. So you would only rob a portion of the atom's velocity.
I'm limiting myself here but just to consider using electricity alone to affect regular matter is a limitation, because everything is more or less electrically neutral given that atoms balance their positives out with negatives. And you can't really change that because then you'd be changing the chemistry of your target and turning them into goo or exploding them wouldn't really be a freeze ray.
Idea 2) A grenade might work if your nanobots came out and slowed down the energetic atoms, kind of like a Maxwell's demon approach. They would rob the surface of whatever they landed on of heat. They would have to do something with that energy like converting it to light and shining it away. Which might be a really cool effect, a huge flash of light and the thing is frozen. Then I guess they would have to self destruct to make the area safe again. But that's not really an ice thrower, either.
Sci-fi idea) The problem is really the way heat works. It's all vibrations of molecules and you have to slow them all down. In order to do that you have to take their motion and put it somewhere else or convert it to another kind of energy. Grabbing their heat is the hard part. It's really sci-fi and out there but if you had a molecular tractor beam and your device was able to transfer that molecular jiggling to your gun, your gun could then get rid of the energy any way it wanted. Maybe the gun forces the atoms into a grid, and all their vibrational energy is transferred to the emitter then.
Here's my last idea and I'll stop, lol) Nanotech exists, right? So that means we must have gotten pretty good with chemical engineering and chemistry and getting things exactly the way we want them. What if we shot a liquid, much like the flamethrower's fuel, but the liquid has an extremely endothermic reaction with oxygen or nitrogen or water, or whatever is available in your world, something common. Chemistry isn't my strong suit so I'll leave it up to smarter people than me to figure that out but it's basically the mirror image of a flamethrower. You have an exothermic reaction with the air in that case, why not an endothermic reaction? That way it would be basically the same thing, just different fuel.