OK, so we have two sun-like stars (I'll just write "suns" from now on) at $100\,\rm AU$ distance, and a (probably earth-like) planet at $1\,\rm AU$ distance from one of the suns. I'll call the sun the planet orbits the "near sun" and the other one the "far sun". I'll assume circular orbits throughout.
Let's first look at the system of two suns. In orbital mechanics, we have
$$\frac{r^3}{(M_1+M_2)T^2}=\frac{G}{4\pi^2}$$
where $r$ is the the radius of the orbit, $T$ is the orbit time, $M_1$ and $M_2$ are the masses of the bodies, and $G$ is the gravitational constant. By inserting the properties of the earth's orbit (and using the fact that the earth's mass is negligible compared to the sun's mass, we get that
$$\frac{G}{4\pi^2} = 1\frac{\mathrm{AU}^3}{M_{\odot}\mathrm{yr}^2}$$
where $M_\odot$ is the mass of the sun and $\rm{yr}$ means year.
So inserting the parameters of the double-sun, we get
$$\frac{(100\,\mathrm{AU})^3}{2M_\odot T^2}=1\frac{\mathrm{AU}^3}{M_{\odot}\mathrm{yr}^2}$$
which means
$$T = \sqrt{500\,000}\mathrm{yr} \approx 700\rm yr$$
In other words, the suns need about 700 years to go round each other. So a human living on your planet would see the far sun move considerably relative to the fixed stars during his lifetime, but never see it return to its original place.
In the following I'll assume that the planet's orbit is in the same plane as the orbits of the suns around each other and going in the same direction, as this (or an approximation of this) is the most probable situation.
Now let's look at the gravitational effects of that far sun on the planet. I'll give all accelerations in units of the acceleration the near sun's gravitation causes for the planet (that is, the acceleration the planet would experience if there would be no far sun), which I'll call $a_0$, and which is
$$a_0 = \frac{GM_\odot}{1\,\mathrm{AU}^2} = 4\pi^2\,\frac{\mathrm{AU}}{\mathrm{yr}^2}$$
Let's look at the situation where the planet is between the two suns. Then its distance from the far sun is $99\,\rm AU$, and thus the acceleration caused by the far sun is $a_0/9801 \approx 1.02\cdot 10^{-4} a_0$, in the direction away from the near sun. To put this in comparison, Jupiter has a mass of about $10^{-3}M_\odot$ and a minimal distance to the Earth of about $4\,\rm AU$, giving rise of a gravitational acceleration of about $2.5\cdot 10^{-4}a_0$. That is, the far sun's gravity affects the planet less than Jupiter affects Earth.
Then, let's look at the brightness of the far sun. The brightness is usually given by the apparent magnitude. The Sun's apparent magnitude (and thus the apparent magnitude of the near sun) is about $−27$. Now by definition a factor $100$ in brightness corresponds to a difference of $5$ in apparent magnitude, and since the brightness goes down with the square of the distance, the far sun at $100$ times the distance has a brightness of $1/10\,000$ of the brightness of the near sun, therefore the far sun would have an apparent magnitude $10$ higher than that of the near sun, that is, $-17$. The moon has an apparent magnitude of $-13$, so the far sun would be about 40 times as bright as the full moon. This means you might be able to see it even on the day sky, as long as it is not too close to the near sun.
Finally let's look at what it would look like. The size (angular diameter) of the Sun, as seen as the Earth, is about half a degree. The far sun is 100 times as far, so the size will be 1/100 as large, or about 20 arc seconds. That's about the same as Jupiter as seen from Earth.
So the far sun would basically look like an extremely bright planet. In particular it's still large enough that it doesn't twinkle.