Seconding the comment to read Ignition. I recommend getting a hardcopy - thank goodness it's back in print now! - but it's available online: https://library.sciencemadness.org/library/books/ignition.pdf; scroll down to page 191 for a good summary of propellant types. As long as your aliens are in our universe, with the same subatomic particles and the same elements, they're going to come up with the same rocket fuels discussed in Ignition. Also, it's hilarious and a great read. One of my favorite quotes is:
[The chemist] then retreats hurriedly to his lair, pursued by the imprecations
of the engineers, who complain that the density is too low ... to which he replies that he'd like a higher density himself, but that he's a chemist and not a theologian and that to change the properties of a compound you have to consult God about it...
In a fictional world, you can play God a bit, though "The aliens used an Unobtainum -hydroxide fuel, which was a non-toxic storable hypergolic monopropellant with a specific impulse of 1500s" is going to get the same kind of eye rolls from chemists as humans taking their helmets off and breathing the air on an unknown alien planet gets from biologists.
The same things will be hypergolic, peroxides will still be persnickety, halogens are still heavy, alcohols won't have enough energy, 12 bar of pressure is no help in keeping oxygen a liquid, and even less so at keeping hydrogen a liquid, and flourine will still consume everything it touches. It may be that some compounds will not be as toxic to your aliens as they are to humans, which will be a boon, but on the other side of that hopefully water vapor or carbon dioxide are not toxic to the aliens because most chemistries will produce a lot of them.
You're going to have to deal with fuels that might be sensitive to SO2/H2S contamination where our rocket engineers have to deal with fuels suffering from oxygen or water contamination. Sulfur in particular is a nasty contaminant, RP1 rocket fuels is basically just a grade of kerosene with very low sulfur and atomic masses kept near C12; we can find natural petroleum deposits with low sulfur but I suspect your aliens may be unable to do so.
Also, you may have a phase change for a few fuels, something that's true at 1 bar and 20C may not be true at 12 bar and 55C. For one example, hydrazine becomes a solid at 2C, so we don't use it as a fuel on an ICBM carried by an arctic submarine because turbopumps don't work well with solids: your aliens probably wouldn't be bothered by that. For another example, propane is a liquid at 10 bar; we don't use it because it's inferior to methane (if you're using a cryogenic fuel) or RP1 kerosene (if you're using a fuel that should be liquid at room temperature). But RP1 would (I think?) be a gas at 55C and therefore unsuitable for its current uses.
Do be aware that Ignition was written in the 70s. The original engines on which the Space Shuttle was based had been around for a while, but it was still a decade before the Shuttle would fly and four decades before SpaceX and other modern spaceflight organizations would fly. Chemistry hasn't changed in the intervening years, there have been no paradigm-shifting discoveries, but chemical engineers and especially controls engineers have gotten better. We can now generate fuels with higher purity, throttle engines much more deeply, and pilot rockets much more precisely, to the point of being able to land a booster propulsively. The 2018 reprint doesn't update any of the chemistry.