Back in time to year 0: how do I produce acetone?

I'm stuck back in time, in the year zero, and lost in India; I need acetone, but how do I produce it? Also, I must avoid contact with people for safety reasons, so I'm living alone.

• You should mention what use your protagonist has for acetone as someone may be able to suggest a more practical alternative to get the job done. – StephenG Jun 18 '20 at 21:22
• Maybe your hermit has diabetes and breath smell like nail polish but don't worry they are not contagious ;D – user6760 Jun 18 '20 at 23:39
• There never was a year 0, we began with year 1. – les Jun 19 '20 at 9:52
• @les year zero was 1975 en.wikipedia.org/wiki/Year_Zero_(political_notion) – Pete Kirkham Jun 19 '20 at 11:34
• @les Don't tell astronomers that there was never a year 0. And we didn't begin with year 1 either. Our way of counting years started hundreds of years after the year which was later numbered as 1. – Abigail Jun 19 '20 at 12:59

With no starting tools this is a big undertaking for your loner, but with the right skill set you could do this with the natural elements you would expect to find almost anywhere in India.

In any such suvival setting, you will first want to make some basic stone tools: an axe, a chisel and a hammer. This will involve a lot of time spent at the river or beach grinding wet stones together into sharp edges (you don't want to use napping for these tools or the edges will be too acute and serrated which will break when used on wood.) For handles, you can use either fire boring or halved, bent, and bound bamboo. These will help you both with the subsequent steps and with all the other things you will be doing to survive such as gathering fire wood, building a shelter, making traps, etc.

Once you have some basic tools and survival needs met, you will need to make a basic barrel for making alcohol in. A bamboo tube would probably be the easiest way to make one, but fire boring a log or making a clay jug would also work. Either which way you will want your stone tools to carve a wooded cap to seal it with. You can use any local grasses for the brewing so you are not cutting into your edible fruit. You will want to start soaking those early on since it will take a while to grow a decent yeast culture. Once you have your yeast culture you can start brewing some grass alcohol in the barrel. Once your have your alcohol, you will need to open up the barrel and let it breath so that it turns to vinegar.

Then you use the vinegar to dissolve something with a lot of Calcium Carbonate such as limestone, eggshells, or marble. Most natural settings in India will contain at least one of these. This reaction will form Calcium Acetate crystals.

Normally Calcium Acetate is distilled in a glass apparatus, but using clay harvested from your natural environment, you could make a similar apparatus out of ceramics. First you would make a kiln out of clay, then you would create the dry distillery out of more clay and fire the one in the other to harden it. It would be a bit of a hard shape to make, but if you do it in multiple sections, you can seal the parts together with mud when doing your distilling. At this point, it is important to keep in mind though that basic earthenware clay will not be suitable to contain the acetone. If your clay is porous, your acetone will evaporate through your container; so, to contain and store the acetone, you will need to double fire it with a second round of ash glaze. This will give your ceramics a glassy exterior with the same resilience to evaporation and corrosion as using a more modern glass solution.

The Calcium Acetate crystals you grew then need to be ground up and dry distilled which will separate the Calcium Acetate back into Calcium Carbonate and Acetone. The Acetone will be released as a gas that will gather in a top chamber, then be captured and separated through condensation.

• Limestone is not necessarily near the ocean. Today, limestone forms in shallow sea, but that's not accessible unless you're going to do underwater mining. What you want is any kind of limestone. The top half of Mount Everest is made of limestone, so no need to be next to the ocean. – Gimelist Jun 19 '20 at 2:30
• What a great answer this is! I think one could shortcut some steps, as year 0 was already the late bronze age, some technic would be available for buying or exchanging. If the character really wants to stay away from each and any human, well yes, he will spend 30 years blowing glass with inappropriate tools. :-) those 30 years of tryouts could be great merchandise at that time though, so some outsourcing is possible. – Anderas Jun 19 '20 at 4:45
• @Anderas Heck, even producing the charcoal is a challenge not easily understood. Even with an understanding of the basic principles, it took ages for people to produce large amounts of charcoal. Given how many attempts you'll need to get reasonably proficient at each step, you're looking at a lot of woodcutting (using what tools?). And that's just for the charcoal! – Luaan Jun 19 '20 at 9:26
• @Anderas, depends on calendar. Assuming year 0 means first year in the calendar for the jews it would be early Bronze Age, but for North Koreans it was little bit more than a century ago. – user28434 Jun 19 '20 at 9:30
• @Anderas The year is not nearly as important as being alone. With being dropped back in time and forced to live alone, 1BCE is functionally no different than 100,000 BCE other than some climate and wildlife differences. – Nosajimiki Jun 19 '20 at 13:17
1. There was no year zero. The current numbering of the years was invented in the 6th century; they had no idea of zero-based numbering in the 6th century. The year before 1 CE is counted as 1 BCE.

2. Historically, acetone was originally made (by Andreas Libavius, at the beginning of the 17th century) by the distillation of lead sugar (aka lead acetate). You can make lead acetate by boiling lead in vinegar.

3. I have no idea from where you can get lead and vinegar, and distillation apparatus, and the cauldrons to boil the lead etc. without entering into contact with people. The did not have Amazon and Ebay in the 1st century.

• This needs more detail to be a useful answer. – rek Jun 19 '20 at 4:18
• The question asks how to produce acetone. The closest that this post gets is to mention the reactant from the first known synthesis and isolation, and only does that as part of a historical note. This doesn't actually answer the question at all. – Nij Jun 19 '20 at 5:40
• Maybe it's absolute timescale. And year zero is about when the Big Bang happened, and the "time" began "existing". There were no India back then though. And even the physics was different. – user28434 Jun 19 '20 at 9:24
• Vinegar and lead were at least known and widely used back then. A distillation apparatus? Not so much. – Luaan Jun 19 '20 at 9:28
• ISO 8106 uses a year 0 (equal to 1 BC). Astronomers use year 0 as well. – Abigail Jun 19 '20 at 13:07

I'd like to build on the excellent answer from NosaJimiki, because although the first steps are pretty good, I think it goes off the rails a little with needing to reinvent the iron age. Resources needed: A forest, some stone, some clay

Step 1) Stone age tools - You will need a round, bowl shaped stone, a large, flat stone, and a sort of trough shaped stone. I'd suggest painstakingly grinding softer stones with harder stones over several weeks.

Step 2) Wooden tools - You will need a digging stick, a firebow, two long forked sticks, two short forked sticks, and two poles. These can probably be broken off trees

Step 3) Dig some pits. Line pits with clay, to keep the water in

Step 4) Gather a massive quantity of fruit: Berries, crab apples, grapes, whatever is around and that you don't want to eat.

Step 5) Mash fruit in pits. Leave to ferment in the open air

Step 6) While fruit is fermenting, raid bird's nests for eggshells. This will be messy, and may get you attacked by eagles, sparrows, hawks, etc.

Step 7) Once pits smell like vinegar, add eggshells until eggshells no longer dissolve.

Step 8) Allow water to evaporate from pits. You can gently help this along by adding warm stones from the fire

Step 9) Crystals should start to form. Save these. Dry them as much as possible

Step 10) lay out your still: Put the stone bowl where you'll build your fire. Position the flat stone above it, angled towards the stone trough.

Step 11) Start your fire, and in small batches, add the crystals. Acetone will start to evaporate off them, hit the flat stone, condense, then run into the trough. You'll want to do this a little at a time, giving the flat stone time to cool down

Then, you have (probably impure) acetone!

If this isn't pure enough, a fractional still could be made by boring a hole (use a hot stone on the end of a stick, or a shell, through a large piece of bamboo. The ridges on each side would act as steps to condense the liquid on. No need to invent the iron age!

Answer: Get some decomposing vegetation, put it in a pig's bladder - wait.

Quote

"...acetone occurs naturally in the environment through decomposing vegetation..." https://badacetone.weebly.com/risks-and-benefits.html

• Dam.... Can't much simpler that that. – user76488 Jun 19 '20 at 2:08
• Formaldehyde occurs naturally in the blood, but telling someone who needs pure formaldehyde to "just open a vein" seems very unhelpful. – Nij Jun 19 '20 at 5:41
• Have you considered the problem of separating the small amounts of acetone from all the other materials left by this process ? To make this a useful answer you need to explain how to do that in the time period the author is interested in. – StephenG Jun 19 '20 at 5:50
• @Vesrie It only looks simple because it's missing a critical step - separation and concentration. That's the hard part of most chemical processes. – Luaan Jun 19 '20 at 9:29
• The OP hasn't specified quantity or purity. We need to know what the acetone will be used for. – chasly - supports Monica Jun 19 '20 at 9:59

Brush up on your biology/chemistry & glass making skills and you might be able to copy the WW1 technique of acetone-butanol-ethanol fermentation for making cordite.

And somewhere to grow sugar cane for the sugar.

• You need to expand this answer more to explain what that process is and why it may be practical in the relevant time period. – StephenG Jun 19 '20 at 17:32
• And to explain why cordite is relevant to the question. – Draft 85 Jun 20 '20 at 9:47