There are a number of physics principles at play here.
1 - The ring world is not "full" of air. The Barometric formula tells us how to model the distribution of 1 atmosphere of air in 1 G worth of gravity. Your ring world does not have exactly 1 G so this is only going to be an approximation but a very close one. If you graph out the Earth's atmospheric density by elevation, you'll see that a significant majority of the air is going to be in the bottom 20km of your ring's walls and reach an approximately space like vacuum by about 100km, but your ring has ~1609km tall walls. If you were to evenly distribute your atmosphere inside of that space, you'd be at 0.512% of Earth's atmospheric density. Not truly a space like vacuum, but close enough for most practical purposes that most people would consider the ring decompressed before you actually lose any meaningful amount of air.
2 -There is no such things as a mathematical point of complete depressurization, when you use a decompression algorithm we measure how long it takes to go from one air density to another. You lose pressure slower as you approach zero without ever hitting zero; so, hitting an uninhabitable atmosphere, and hitting the density of space are two VERY different time scales.
3 - Air can never decompress faster than the speed of sound. Most decompression algorithms don't account for this because they measure for a small vessel losing air through a hole small enough for this to not be an issue. Mathematically, this station should be able to lose 1/2 of its air in just a few seconds, but it's air can't move fast enough to cover the hundreds of miles it takes to even get to any holes in your ring in that amount of time.
4 - When your ring breaks apart, the pieces will be going about 40 times the rotational speed of the Earth sending the fragments off into deep space and taking away your artificial gravity. This lose of gravity means that your air is not going to be pouring towards your side holes nearly so much as it will be dissipating upward and out the top.
5 - The ring is under a LOT of tension. While it's easy to say scrith makes hand waving away that much stress possible, any breaking apart that it might do would be violent. Like a giant snapping guitar string, you would expect there to be massive waves of oscillations throughout your structure flinging off most of the atmosphere in an instant, large sections of the ring would curl or crumble and everything would be so chaotic on such an incompressible scale that without a very detailed explanation of scrith's properties, it would be very hard to say what would happen. For purposes of this question, I will assume scrith is also infinitely rigid otherwise the answer to this question becomes very open-ended.
Given all these factors, we know we can not use a typical decompression algorithm because we first need to find out just how long it's going to take for the air to expand to fill the ring before it can even start to escape.
Since the upper atmosphere will expand slower than the higher density lower atmosphere, we can get away with simplifying this equation by averaging out the starting atmosphere and still get a very close answer to if we tried to model out the exact expansion of a non-linear gradient pressure since it will all diffuse pretty evenly by the time it expands enough to reach the top of your wall.
- Density of air is @ sea level = 1.225 kg/m3
- The mass of Earth's atmosphere = 10,092.139 kg/m3
So, we can estimate you have a starting body of gas that is 8238.481 meters high at a density of 1.225 kg/m3 that will expand as fast as it can upward to get out of the ring.
Next we need to come up with a decompression formula that works for the speed of sound as you loose density. The air at 1 atmosphere of pressure can expand at a rate of ~344 m/s, but as air loses density, it will expand slower. So by the time your atmosphere's averaged height doubles to about 16,476m, the rate of expansion will be halved to about 172m/s, so on and so forth.
Below is a simple JavaScript program that calculates this:
<div id="output"></div>
<script>
speed = 344;
height = 8238.481;
startheight = 8238.481;
endheight = 1609340;
time = 0;
while (height < endheight){
if (height*2 < endheight){
period = 2;
heightC = height;
} else {
period = endheight / height;
heightC = endheight - height;
}
time += heightC/-((1-Math.log(2)*speed)-speed);
height *= period;
speed *= 1/period;
}
document.getElementById("output").innerHTML = 'FILLS RING AT<br>Time: ' + Math.round(time) + ' sec<br> Height: ' + Math.round(height/1000) + ' km<br> End Speed: ' + speed.toFixed(5) + ' m/s<br>Pressure: ' + (startheight/endheight).toFixed(5) + 'Atm';
- FILLS RING AT
- Time: 241626 sec
- Height: 1609 km
- End Speed: 1.76099 m/s
- Pressure: 0.00512Atm
This means, if you could find a way to restore gravity within 2.8 days, you'll be able to keep most of the air just fine. However, by this point your fragment has already drifted out of the Goldilocks zone and pressure has dropped so much everyone is dead.
That said, the edge of the Earth's atmosphere @ 100km (The point we start to call space) has a pressure of .00001 atmospheres. So a to get to this point, you make this change:
endheight = 823848100;
Ooops, the time output for this blows WAY past the max float size allowed in JavaScript; so, need to run these calcs in something that allows for larger numbers to give you an exact answer, but let's just say it is a very very long time. Someone else with access to MATLAB or something similar can probably get you an exact answer, but this gets you close enough to what you need for your story.
One last factor is gravity. In a smaller fragment, there will not be enough gravity to matter, but let's you have a nice big chunk of the ring. Like in the picture below. The ring's gravity will actually make you lose your atmosphere ever so slightly faster because your center of gravity will be above the surface of the ring. The good news is though, that your atmosphere will eventually coalesce into icy planet. For a 1/3rd segment like the image below, this will result in frozen gas planet about the mass of Earth.

To answer your question about salvageability, the shape of the ring fragment would make it a useless habitat, but a future civilization may perhaps scrap parts of it to make a much smaller halo superstructure around the Earth sized gas planet. They could mine the ice ball for a nearly inexhaustible source of water, air, and hydrogen to run their fusion reactors for power, and the ring fragment could give them all the soil, metals, and minerals they would need.
As for you new requirement: "This is thrust induced, necessary to hold them in an orbit closer to their primary than it should be at its orbital velocity." While this new requirement pretty much kills my answer, I will leave this up as a point of reference for future inquiries that may not rely on propulsion to maintain the orbit.